1. Chemical Kinetics………………………………………. 07
1.1 Introduction
1.2 Third-order reactions
1.3 Examples of third-order reaction
1.4 Characteristics of third order reaction
1.5 Methods to determine the order of reaction using: Integrated rate equation method, Graphical method,Half-life method, Differential method.
1.6 Effect of Temperature on Reaction Rates
1.7 Temperature Dependent of reaction rate and Arrhenius equation.
1.8 Solved Problems.
2. The First Law of Chemical Theromodynamics………………. 24
2.1 Introduction
2.2 First law of thermodynamics
2.3 Enthalpy
2.4 Heat capacity
2.5 Relation between Cp and Cv
2.6 Expansion of ideal gas and changes in thermodynamic properties,
Isothermal process, Adiabatic process
2.7 Limitations of the first law
2.8 Need for the second law of thermodynamics
2.9 Cyclic process
2.10 Carnot cycle
2.11 Second law of thermodynamics
2.12 Concept of entropy
2.13 Entropy change in isothermal expansion, Reversible and irreversible processes
2.14 Phase change and entropy
2.15 Entropy of mixing of ideal gases
2.16 Work and free energy function
2.17 Solved Problems.
3. Electrolytic Conductance ………………………………. 57
3.1. Introduction
3.2. Electrolytic Conductance
3.3. Specific and equivalent conductance
3.4. Variation of equivalent conductance with concentration
3.5. Kohlrausch’s law and its applications
3.6. Migration of ions and ionic motilities
3.7. Transport number determination
3.8. Relation between ionic mobility, ionic conductance and transport number
3.9. Ionic theory of conductance
3.10. Solved problems
4. Phase Equilibrium ……………………………………. 82
4.1 Introduction.
4.2 Phase, Component and Degree of freedom of a system.
4.3 Stability of phases.
4.4 Criteria of phase equilibrium.
4.5 Gibb’s phase rule and its thermodynamic derivation
4.6 Phase diagram of one component system:
Water system: Carbon dioxide system: Sulphur system
