Fundamental of Chemistry – II

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The first edition of CHE 151-T (MJ) Fundamentals of Chemistry – II, under faculty of Science and Technology, Savitribai Phule Pune University Pune, according to new syllabus implemented from year...

Name : Fundamental of Chemistry – II
Vendor : Prashant Publication
Type : F.Y.B.Sc. Sem. II CHE-151-T
Barcode : 9789348537225

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INTERNATIONAL	XS	S	M	L	XL	XXL	XXXL
EUROPE	32	34	36	38	40	42	44
US	0	2	4	6	8	10	12
CHEST FIT (INCHES)	28"	30"	32"	34"	36"	38"	40"
CHEST FIT (CM)	716	76	81	86	91.5	96.5	101.1
WAIST FIR (INCHES)	21"	23"	25"	27"	29"	31"	33"
WAIST FIR (CM)	53.5	58.5	63.5	68.5	74	79	84
HIPS FIR (INCHES)	33"	34"	36"	38"	40"	42"	44"
HIPS FIR (CM)	81.5	86.5	91.5	96.5	101	106.5	111.5
SKORT LENGTHS (SM)	36.5	38	39.5	41	42.5	44	45.5

The first edition of CHE 151-T (MJ) Fundamentals of Chemistry – II, under faculty of Science and Technology, Savitribai Phule Pune University Pune, according to new syllabus implemented from year 2024-2025, as per National Education Policy – 2020.

This book is written as per New syllabus introduced from 2024-25. We have tried to explain the concepts and information in easy language so that students could understand it easily. We feel that the information is presented in a simple form for the better understanding of students.

This book includes explanation for each point, number of illustrative examples are given and exercise is given at the end of each topic for the benefit of students. In our view the book will fulfil the expectations of students and teachers.

1. Photochemistry ……………………………………………. 07
1.1 Introduction
1.2 Difference between Thermal and Photochemical Processes
1.3 Laws of Photochemistry
1.3.1 Grotthus-Draper Law (First Law of Photochemistry)
1.3.2 Stark-Einstein Law (Second Law of Photochemistry)
1.4 Quantum Yield
1.4.1 Reasons for High and Low Quantum Yield
1.4.2 Factors affecting Quantum Yield
1.4.3 Experimental Method for the Determination of Quantum Yield
1.5 Fluorescence
1.6 Phosphorescence
1.7 Chemiluminescence

2. Chemical Kinetics ………………………………….. 26
2.1 Introduction
2.2 Rate of a reaction (Average and instantaneous), order and Molecularity
of a reaction
2.3 Rate law
2.4 Specific rate constant, First order and Pseudo molecular reaction
(Without derivation).
2.5 Order and Molecularity
2.6 Factors influencing the rate of reaction
2.7 Pseudo – Order reactions
2.8.1 First Order Reactions
2.8.2 Characteristics of first order reaction
2.9 Second order reaction
2.9.1 Mathematical equation
2.9.2 Characteristics of Second Order Reaction
2.10 Numerical based on rate of reaction, half-life period and rate constant of
First order reaction only.

3. Periodicity ………………………………………… 43
3.1 Introduction
3.2 The long form of periodic table. s, p, d, f block elements
3.3 Properties of the Element
3.3.1 Effective nuclear charge
3.3.2 Atomic radii (van der Waals)
3.3.3 Ionic radii.
3.3.4 Ionization enthalpy
3.3.5 Electron gain enthalpy; trends of electron gain enthalpy
3.3.6 Electronegativity
3.3.7 Oxidation states of elements

4. Stereochemistry …………………………………… 70
4.1 Concept and Types of isomerism
4.2 Structural isomerism
4.3 Projection Formulae
4.4 Stereoisomerism
4.5 Optical activity and chirality
4.6 Elements of symmetry
4.7 Optical isomerism
4.8 Nomenclature of optical isomerism
4.9 Geometric isomerism.

5. Chemical Bonding ………………………………………….. 97
5.1 Introduction to Atomic Orbitals
5.2 Multiple Bonding: σ, π, and δ Bond Approach
5.3 Valence Bond Theory (VBT)
5.4 Concept of Hybridization
5.5 Bent Rule
5.6 Valence Shell Electron Pair Repulsion Theory (VSEPR)
5.7 Shapes of Simple Molecules and Ions