Section – I
PHYSICAL CHEMISTRY – I
A. Chemical Kinetics (Any two)
Experiment No. 1……………………………………………………………………………………………………… 15
To determine the order of reaction between K2S2O8 and KI by half life method.
Experiment No. 2……………………………………………………………………………………………………… 20
To determine Energy of activation of the reaction between K2S2O8 and KI with unequal
initial concentration.
Experiment No. 3……………………………………………………………………………………………………… 25
To study the kinetics of saponification reaction between sodium hydroxide and ethyl acetate.
Experiment No. 4……………………………………………………………………………………………………… 28
To Study the Effect of concentration of the reactants on kinetics of acid hydrolysis of an ester.
Experiment No. 5……………………………………………………………………………………………………… 31
To study the kinetics of iodination of acetone.

B. Thermodynamics (Any Two)
Experiment No. 1……………………………………………………………………………………………………… 35
Determination of heat capacity of calorimeter for different volumes.
Experiment No. 2……………………………………………………………………………………………………… 38
Determination of enthalpy of neutralization of hydrochloric acid with sodium hydroxide.
Experiment No. 3……………………………………………………………………………………………………… 42
Determination of enthalpy of ionization of acetic acid.

C. Electrolytic Conductance (Compulsory)
Experiment No. 1……………………………………………………………………………………………………… 49
To determine the cell constant of a given cell using 0.01 N KCl solution and hence
determine the dissociation constant of a given monobasic weak acid.

Experiment No. 2……………………………………………………………………………………………………… 52
To investigate the conductometric titration of any one of the following (a) strong acid
against strong base, (b) strong base against weak acid (standardization of base must be
performed with KHP).

Section – II
INORGANIC CHEMISTRY
A. Synthesis of Coordination compounds (Any three)
Experiment No. 1……………………………………………………………………………………………………… 59
Synthesis of sodium cobaltinitriteNa3[Co(NO2)6] (a laboratory chemical) from Co(II)
salt and NaNO2 salt. Comment on colour and magnetic properties of the complex.
Experiment No. 2……………………………………………………………………………………………………… 62
Synthesis of potassium trioxalatoferrate (III) trihydrate, K3[Fe(C2O4)3] 3H2O.
Comment on colour and magnetic properties of the complex.
Experiment No. 3……………………………………………………………………………………………………… 65
Synthesis of tris (acetylacetone) iron (III), [Fe(acac)3] by green chemistry method
by reaction between Fe(OH)3 and acetyl acetone. Comment on colour and magnetic
properties of this complex.
Experiment No. 4……………………………………………………………………………………………………… 68
Synthesis of hexamminenickel (II) chloride, [Ni(NH3)6]Cl2 from NiCl2.6H2O.
Comment on colour and magnetic properties of the complex.
Experiment No. 5……………………………………………………………………………………………………… 71
Synthesis of tetramminecopper (II) sulphate monohydrate, [Cu(NH3)4]SO4H2O.
Comment on colour and magnetic properties of complex.
B. Inorganic colorimetric investigations (Any two)
Experiment No. 1……………………………………………………………………………………………………… 76
Estimation of Cu(II) by complexation with R-Nitrso salt/ammonia by colorimetry.
Determination of linearity range for Cu(II) using different ranges of Cu(II) concentrations
and verification Beer’s law..

Experiment No. 2……………………………………………………………………………………………………… 79
Prepare solution of Fe(III) and SCN– in different molar proportion, record their
absorbance and calculate equilibrium constant of [Fe(SCN)]2+ complex.
Experiment No. 3……………………………………………………………………………………………………… 82
Solutionstate synthesis of [Ni(en)3]2+ complex and i) determination of λmax and
calculate 10Dq ii) determination of equilibrium constant of the same complex.

C. Determination Metal Ligand Ratio (Any One)
Experiment No. 1……………………………………………………………………………………………………… 85
Determination Metal ligand ratio of Potassium Tris(oxalate) Fe(III) complex.
Experiment No. 2……………………………………………………………………………………………………… 90
Determination Metal ligand ratio of Fe(III) or Cu(II)–Salicylic acid complex by
colorimetric method.

D. Determination of transition metal ions by paper chromatography
using colour forming ligands
Experiment No. 1……………………………………………………………………………………………………… 93
Determination of transition metal ions by paper chromatography using colour forming
ligands.