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the book on Handbook of Practical Chemistry for Undergraduates: Volume II in the hands of students learning chemistry at undergraduate level and the teachers of chemistry. The book is written...

  • Name : Handbook of Practical Chemistry for Undergraduates : Volume - II
  • Vendor : Prashant Publication
  • Type : General
  • Manufacturing : May 2026
  • Total Pages : 310 Pages
  • Barcode : 9789377767464

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Handbook of Practical Chemistry for Undergraduates : Volume - II
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the book on Handbook of Practical Chemistry for Undergraduates: Volume II in the hands of students learning chemistry at undergraduate level and the teachers of chemistry. The book is written by keeping in mind curriculum of chemistry prescribed by UGC taught at different levels. In Volume II of the handbook, we have tried to cover experiments of the of third year level of students of B. Sc. Practical chemistry is the core part of curriculum of chemistry. Therefore, we have included about 90 experiments in this handbook. The handbook includes different experiments of physical chemistry, organic chemistry, inorganic chemistry and analytical chemistry.
Experiments of physical chemistry include both, instrumental and non-instrumental practicals. The instrumental experiments from physical chemistry include potentiometry, conductometry, pH metry, polarimetry, flame photometry, refractometry and colorimetry. Non-instrumental practicals include, kinetics, viscosity, etc.
Experiments of organic chemistry include Separation of binary mixture and Organic Qualitative Analysis, organic preparations and organic estimations. Green chemistry preparations and preparation of derivatives are also included. Experiments of inorganic chemistry include Inorganic Qualitative Analysis, volumetric analysis, gravimetric analysis and inorganic preparations.
The book focuses on understanding the principle involved in different experiments. The experiments include the theory behind experiment, reactions involved, labelled diagrams, procedures, calculations, literature required and results. Preparation of solutions required for each experiment are given in details including quantity of reagents required. Procedures of experiments are simple and given in details considering level of students. Calculations are also given in details. Precautions required while performing experiments are also given wherever necessary. Diagrams are well labelled for better understanding of the students.

To develop interest of learners, at the end of experiments, questions are also given. The literature required for experiments is also given. In case of some experiments, standard results like melting points of compounds are also provided.
Considering the depth of students, book is written in very simple language and unnecessary explanation is avoided. It will definitely generate interest of the learner in understanding of the experiments. I hope this book will be useful for the undergraduate students of chemistry.

Physical Chemistry Experiments
1. Conductometric titration of mixture of acids and hence determine the strength of acids....................1

2. Determine the degree of hydrolysis and hydrolysis constant of sodium acetate conductometrically................5

3. Determination of relative strength of monochloro acetic acid and acetic acid by conductometry............10

4. Determine basicity of organic acid by conductometry measurement...........14

5. Determination of Ecal and pH of buffer solution (Citric acid+Na2HPO4) using quinhydrone electrode...........18

6. Determine the pKa and Ka of weak monobasic acid by
potentiometric titration.......................................22

7. Determine the amount of sodium chloride in a given solution by potentiometric titration with silver nitrate.......28

8. Determination of formal redox-potential of Fe++/Fe+++ by Potentiometric titration...................................33

9. Determine the amounts of aspirin in the given tablet by pH metrictitration...................38

10. Determine the pKa of various mixtures of sodium acetate acetic acid in aqueous solution and hence to find the dissociation constant......................44

11. Determination of pKa and Ka values of a given weak acid by pH metric titration with strong base.............48

12. Determination of hydrolysis constant of aniline hydrochloride by pH-measurements.............................52

13. To study the kinetics of inversion of cane sugar by polarimeter...................55

14. Determination of the concentration of a given solution of optically active substance (cane sugar) by polarimetric measurements................................57

15. Determine the percentage of two optically active substances (d-sucrose and d-tartaric acid) in a mixture polarimetrically...............................................59

16. Estimation of Na, K, Li an Ca by flame photometer in given sample...........64

17. Determine the refractive indices of series of KCl solution and hence unknown concentration of given KCl solution.......................68

18. Determination of refractive index of four liquids and hence determine its specific and molar refraction.....73

19. Determine the molar refraction of homologues methyl, ethyl, propyl alcohol & show that constancy configuration to molar refraction by CH2_ group.....76

20. Study the hydrolysis of methyl acetate in presence of hydrochloric acid.....80

21. Determine the energy of activation of the reaction between K2S2O8 and KI..............84

22. Investigate the kinetics of iodination of acetone (zero order reaction)........88

23. To investigate the reaction between H2O2 and KI by gas burette method....92

24. Determine the order of the reaction between potassium persulphate and potassium iodide by fractional
change method............................................95

25. Determination of molecular weight of high polymer using its solution of different concentration by viscosity measurement......................................100

26. Determination of radius of glycerol sucrose molecule by viscosity measurement................................104

27. Determine the distribution constant of iodine between water and carbon tetrachloride. Hence find the molecular condition of iodine in carbon tetra chloride.................108

28. Determination of λmax concentration of given solution of Cu2+ ions and verify Beer’s law.....................111

29. Verify Beer’s law, determine molar extinction coefficient of Potassium permanganate...................115

30. Determination of Emax of b particles.............122

Inorganic Chemistry Experiments
1. Inorganic qualitative analysis of mixture containing two basic and two acidic radicals................126

2. Estimation of iron volumetrically from heamatite ore................................151

3. Estimation of manganese from pyrolusite ore volumetrically.....................154

4. Estimation of calcium volumetrically from dolomite ore............................159

5. Estimation of Zinc from Brass alloy by EDTA method...............................162

6. Estimation of copper iodometrically from Nichrome alloy.........................166

7. Determination of iron from the given sample of stainless steel..................168

8. To determine the amount of copper present in given solution of copper sulphate by colorimetric titration using standard solution of EDTA..........171

9. Estimation of titanium using hydrogen peroxide by colorimetry................174

10. Estimation of iron using Thiocyanate method by colorimetry....................178

11. To determine the concentration of cobalt in the given solution using R-nitroso salt by colorimetry...................181

12. Gravimetric estimation of Fe as Fe2O3...............184

13. Gravimetric estimation of zinc as zinc pyrophosphate (Zn2P2O7).............188

14. Estimation of lead as lead chromate (PbCrO4),
(By Gooch crucible method).........................191

15. Estimation of Aluminium as aluminium oxide (Al2O3) gravimetrically.....194

16. Estimation of manganese by Volhard’s method.........197

17. Estimation of Nickel by EDTA method..........................201

18. Determination of strength of NaOH and Na2CO3 in a given solution........203

19. Estimation of ferrous and ferric by redox titration by dichromate method...208

20. Preparation of Bis (ethylenediamine) copper (II) sulphate........................213

21. Preparation of Potassium trioxalato chromate (III) complex.....................214

22. Preparation of Tris (acetylacetonato) iron (III)...........216

23. Preparation of hexaaquonickel (II) chloride: [Ni(H2O)6] Cl2...................218

24. Preparation of potassium tris oxalatoaluminate (III) trihydrate K3[Al(C2O4)3]. 3H2O complex.............220

25. Synthesis of ZnO nanoparticles using Zinc acetate dihydrate....................220

26. Separation and Identification of binary mixture of cations by paper chromatography................222

Organic Chemistry Experiments
1. Separation of binary mixture and qualitative analysis.....227

Organic Estimations
2. To estimate the amount of acetamide present in the given solution............255

3. Estimation of basicity (number of COOH groups) of the given unknown carboxylic acid...................................257

4. Estimation of amount of glycine present in given solution.........................260

5. To determine the Saponification value of an oil in the given solution........262

6. Estimation of Glucose..................................266

7. To estimate the amount of ethyl benzoate present in the given solution.....269

8. Estimation of vitamin C.....................................272

Green Chemistry Preparations
9. Synthesis of dibenzal propanone from benzaldehyde and acetone (Using LiOH.H2O / NaOH)........................274

10. Aniline to acetanilide by using Zn/Acetic acid...........................................276

11. Synthesis of p–bromo acetanilide from acetanilide by using KBr..............277

12. Synthesis of dihydropyrimidinone from ethyl acetoacetate, benzaldehyde and urea................278

13. Diels–Alder reaction between furan and maleic acid [4+2] Cycloaddition Reaction..............................279

Preparation of Organic Compounds
14. Preparation of Benzoquinone from Hydroquinone....281

15. Preparation of Sudan–I.......................282

16. Preparation of p–nitro acetanilide from acetanilide...284

17. Preparation of 2–naphthyl methyl ether from 2 naphthol....285

18. Preparation of Hippuric acid from glycine (Benzoylation)...286

19. Preparation of p–iodo nitrobenzene from p–nitroaniline...........................288

20. m–nitro aniline from m–dinitrobenzene................290

21. Preparation of Benzoic acid from ethyl benzoate..............291

22. Preparation of Adipic acid from Cyclohexanone.............................292

23. Glucosazone from glucose.....................294

24. Isolation of starch from potato................................296

Preparations of derivatives
25. Preparation of Oxime derivative of aldehydes and ketones.......................297

26. Preparation of Aryloxy acetic acid derivative of Phenol............................298

27. Preparation of 2, 4 DNP derivative of aldehyde / ketone...........................299

28. Anilide derivative of Carboxylic acid......................300

Purification Techniques
29. Solvent extraction of binary mixture using separating funnel....................301

30. Separation and purification of the mixture of compounds by using Preparative Thin Layer Chromatography (PTLC) method..................303

31. To obtain pure components from a mixture of organic compounds using steam distillation...................306

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