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The chapters in this book cover all the syllabi points in very simplified way. To make the learning easy we have added figures, reactions and all necessary things which will...

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Organic and Analytical Chemistry
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The chapters in this book cover all the syllabi points in very simplified way. To make the learning easy we have added figures, reactions and all necessary things which will boost students understanding level of the subject. While writing this book care is also taken students should achieve the learning objective of each and every topic as per the curriculum. In every topic application of the given technique is also added which help the student to get idea about relevance of that specific technique in industrial sector and indirectly in our day-to-day life.
The one more feature of this book is that we have added questions at the end of every topic which will provide sights to the students about the type of question which may appear in the examination. In addition, some space is also kept for the students that they can also develop their own questions which will increase their understanding and interest in the subject.

1. Structure, Acidity and Basicity .............................7
1.1 Introduction
1.2 Simple Aliphatic Carboxylic Acids
1.3 Substituted Aliphatic Acids
1.4 Phenols
1.5 Aromatic Carboxylic Acids
1.6 Introduction to Bases
1.7 Aliphatic Bases
1.8 Aromatic Bases
1.9 Introduction to types of organic reactions
1.10 Concept of Reaction Mechanisms
1.11 Energetics of Reactions

2. Reactivity and Reactions of halogenated hydrocarbons...................19
2.1 Introduction
2.2 Classification of Halogen Derivatives
2.3 Nature of C-X Bond
2.4 Methods of Preparation of Haloalkanes
2.5 Preparation of Haloarenes
2.6 Chemical Reaction
1. Nucleophilic Substitution Reaction
I. Substitution nucleophilic unimolecular (SN2)
II. Substitution nucleophilic unimolecular (SN1)
III. Factors af
fecting SN1 and SN2 reactions
2. Elimination Reaction
I. E2 elimination or β-elimination- bimolecular elimination
II. E1 elimination – unimolecular elimination
III. E1cB Mechanism 3. Nucleophilic aromatic substitution (SNAr)
Contents

3. Volumetric Analysis..........................................43
3.1 Introduction
3.2 Classification of reaction in volumetric analysis
3.3 Methods of expressing concentration of solution
3.4 Primary and Secondary Standard Substances
3.5 Theory of indicators
3.6 Acid-Base Titrations
3.6.1 Strong acid-strong base titration
3.6.2 Strong acid-weak base titration
3.6.3 Weak acid- strong base titration
3.6.4 Weak acid - weak base titration
3.7 Reduction oxidation (Redox) titrations
3.8 Complexometric titrations
3.8.1 EDTA titrations
3.8.2 EDTA titration curves
3.8.3 Choice of indicators
3.9 Precipitation Titration

4. Chromatography..................................79
4.1 Introduction to chromatography
4.2 Principle of Chromatographic Separation
4.3 Types of Chromatography
4.4 Paper Chromatography
4.4.1 Introduction
4.4.2 Principle
4.4.3Migration Parameters
4.4.4Types of Paper Chromatography
4.5 Applications of Paper Chromatography
4.6 Separation of Amino acids using paper chromatography
4.7 Thin Layer Chromatography (TLC)
4.7.1 Introduction
4.7.2 Experimental Technique
4.7.3 Aplications of Thin Layer Chromatography
4.7.4 Limitations of Thin Layer Chromatography