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The first edition of CHE-313-MJ - P: Organic Chemistry Practical - I, under faculty of Science and Technology, Savitribai Phule Pune University, Pune, according to new syllabus implemented from year...

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Organic Chemistry Practical-I - CHE-313-MJE
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The first edition of CHE-313-MJ - P: Organic Chemistry Practical - I, under faculty of Science and Technology, Savitribai Phule Pune University, Pune, according to new syllabus implemented from year 2026-27, as per National Education Policy – 2020.
This book is written as per New syllabus introduced from 2026-27. We have tried to explain the concepts and information in easy language so that students could understand it easily. We feel that the information is presented in a simple form for the better understanding of students. This book includes explanation for each point, number of illustrative examples are given and exercise is given at the end of each topic for the benefit of students. In our view, the book will fulfil the expectations of students and teachers.

A : Separation of Binary Mixtures
and Qualitative Analysis.....................................7 to 42
a) Solid : Solid Mixtures
b) Solid : Liquid Mixtures
c) Liquid : Liquid Mixtures
At least one mixture from each of the following categories should be included:
• Acid – Base
• Acid – Phenol
• Acid – Neutral
• Phenol – Base
• Phenol – Neutral
• Base – Neutral
• Neutral – Neutral

B : Organic Preparations.........................................43 to 67
a) Green Chemistry Preparations
1. Solvent-free aldol reaction between acetophenone and p-tolualdehyde.
2. Preparation of benzilic acid under solvent-free (solid-state) conditions.
3. Preparation of p-bromoacetanilide from acetanilide using potassium bromide and ceric ammonium nitrate.
4. Preparation of 5-nitrosalicylic acid from salicylic acid using calcium nitrate.

b) Organic Preparations
1. Preparation of p-iodonitrobenzene from p-nitroaniline by the Sandmeyer reaction.
2. Preparation of methyl orange by diazotization of sulfanilic acid followed by azo coupling with N,N - Dimethylaniline.
3. Preparation of p-chlorobenzoic acid and p-chlorobenzyl alcohol from p-chlorobenzaldehyde.
4. Preparation of anthracene–maleic anhydride adduct via the Diels–Alder reaction.
5. Preparation of acetylsalicylic acid (aspirin) from salicylic acid by acetylation using acetic anhydride.
6. Preparation of 2-amino-4-(4-chlorophenyl)thiazole from 4-chlorophenacyl bromide and thiourea
7. Preparation of 1, 4- dihydropyrimidinone from ethyl acetoacetate, benzaldehyde, and urea using oxalic acid as a catalyst.

C : Preparation of Organic Derivatives.....................68 to 77
1. Oxime derivative of benzophenone
2. Acid derivative of benzamide
3. Hydrazone derivative of acetophenone and phenylhydrazine
4. 2,4-Dinitrophenylhydrazone (2,4-DNP) derivative of benzaldehyde

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