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The first edition of CHE–301–MJ–T Physical Chemistry II, under faculty of Science and Technology, Savitribai Phule Pune University, Pune, according to new syllabus implemented from year 2026-27, as per National...

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Physical Chemistry-II - CHE-301-MJ-T
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The first edition of CHE–301–MJ–T Physical Chemistry II, under faculty of Science and Technology, Savitribai Phule Pune University, Pune, according to new syllabus implemented from year 2026-27, as per National Education Policy – 2020.
This book is written as per New syllabus introduced from 2026-27. We have tried to explain the concepts and information in easy language so that students could understand it easily. We feel that the information is presented in a simple form for the better understanding of students.
This book includes explanation for each point, number of illustrative examples are given and exercise is given at the end of each topic for the benefit of students. In our view the book will fulfil the expectations of students and teachers.

1. Electrochemical Cells.....................................................7
1.1 Introduction
1.2 Origin of the e.m.f
1.3 Conventions used to represent a cell
1.4 Reversible and irreversible Cells
1.5 Measurement of E. M. F.
1.6 Standard cell
1.7 Cell reaction and E.M.F
1.8 Convention regarding sign of E.M.F
1.9 Single electrode potentials
1.10 Nernst Equation
1.11 Thermodynamics and E.M.F
1.12 Electrochemical series
1.13 E.M.F. and equilibrium constant of cell reaction
1.14 Classification of Electrodes
1.15 Liquid junction potential
1.16 Classification of Electrochemical Cell
1.17 Applications of e.m.f. measurements
1.18 Battery
1.19 Fuel cell

2. Nuclear Chemistry.....................................................66
2.1 Introduction
2.2 Radioactivity
2.3 Types of Radiation
2.4 Properties of Radiations
2.5 Detection and Measurement of Radioactivity
2.6 Nuclear structure
2.7 Classification of Nuclides
2.8 Radioactive decay process
2.9 Soddy’s Group Displacement law
2.10 Kinetics of decay
2.11 Nuclear energy
2.12 Applications of Radioactivity

3. Quantum Chemistry......................................................94
3.1 Introduction: Need for quantum mechanics
3.2 Recapitulation: de Broglie hypothesis
3.3 Heisenberg’s uncertainty principle
3.4 Postulates of quantum mechanics
3.5 Time-independent Schrödinger wave equation
3.6 Operators, and observables
3.7 Conditions for a well-behaved wave function
3.8 Particle in a 1-D box
3.9 Particle in a 2-D box
3.10 Particle in a 3-D box
3.11 Physical interpretation of ψ and ψ²
3.12 Degeneracy
3.13 Applications to Conjugated Systems
3.14 Harmonic oscillator and Zero point energy
3.15 Quantum tunnelling
3.16 Numerical

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