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SYBSc Semester IV

CH-402 | Organic and Inorganic Chemistry

S.Y.B.Sc. | Sem IV | Chemistry

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S.Y.B.Sc. | Sem IV | CH-402
Organic and Inorganic Chemistry

We are very glad to present this book on “Organic and Inorganic Chemistry’’ of semester – II in the hands of S.Y.B.Sc. students and teachers. The book is strictly written according to the CBCS pattern syllabus framed by the board of studies in Chemistry, KBC NMU Jalgaon, for Second year B.Sc to be implemented from June 2019 and is written in very simple language giving exhaustive details. Questions of various types are included at the end of each chapter. This will help in generating interest and thorough understanding of the subject. We hope, this book will be useful for students and teachers.

Unit 1 Synthetic Reagents
1.1 Introduction
1.2 Active methylene group
1.3 Ethyl Aceto Acetate (EAA)/Aceto acetic Ester (AAE), 1.3.1 Preparation of Ethyl aceto acetate, 1.3.2 Synthetic applications,
1.4 Malonic Ester (Diethyl malonate), 1.4.1 Preparation of Diethyl malonate, 1.4.2 Synthetic applications.

Unit 2 Organometallic compounds
2.1 Organometallic compounds
2.2 Nomenclature
2.3 Carbon–metal bond in organometallic compounds,
2.4 Organolithium compounds – 2.4.1 Preparation of organolithium compounds, 2.4.2 Preparation of alcohols
2.5 Organomagnesium Compounds (Grignard Reagent) – 2.5.1 Preparation of Grignard Reagent, 2.5.2 Reactions of Grignard Reagent
2.6 Organo copper compounds (Lithium dialkylcuprate) – 2.6.1 Preperation of organocopper compounds, 2.6.2 Synthesis of alkane from lithium dialkyl cuprate
2.7 Organozinc compounds, 2.7.1 Preparation of organozinc compounds, 2.7.2 Synthesis of Cyclopropanes (Simmon–Smith reaction),
2.7.3 Reformatsky reaction

Unit 3 Molecular Orbital Theory (MOT)
3.1 Introduction
3.2 Theories of covalent bond
3.3 Types of combination or overlap of Atomic orbitals–Five types of combinations, 3.3.1 Non bonding combination of orbitals 3.3.2 Rules for Linear combination of atomic orbitals,
3.4 Molecular orbital Energy Level Diagrams (MO diagrams)
3.5 MO theory of Homonuclear Diatomic Molecules
3.6 MO theory of Hetero-nuclear diatomic molecules


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