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SYBSc Semester III

CH-301 | Physical & Analytical Chemistry

S.Y.B.Sc. | Sem III | Chemistry

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S.Y.B.Sc. | Sem III | CH-301
Physical & Analytical Chemistry

We are very happy to hand over this text book of S.Y.B.Sc. Physical and Analytical Chemistry to S.Y.B.Sc. students. This book has been presented to you according to the revised syllabus of Savitribai Phule Pune University implemented from June 2020.
An attempt is made to give more emphasis on essential modern concepts in chemistry. The concepts are illustrated and elaborated with necessary examples. Sufficient exercise is given at the end of each topic for the practice of the students.

1. Chemical Kinetics 
1.1 Molecularity of a reaction
1.2 Order of a reaction
1.3 Rate of reaction
1.4 Factors affecting the reaction rates
1.5 Rate laws
1.6 Zero order reaction
1.7 First order reaction
1.8 Second order reactions
1.9 Methods for determination order of a reaction
1.10 Arrhenius Equation
1.11 Effect of Temperature on Reaction Rates
1.12 Deviation of Arrhenius Equation
1.13 Evaluation of energy of activation
1.14 Reaction Dynamics
1.15 Collision theory of bimolecular reactions
1.16 Bimolecular Reactions in solutions (Probability factor)
1.17 Weakness of Collision Theory
1.18 Transition State Theory
1.19 Mathematical treatment of Transition State Theory

2. Surface Chemistry 
2.1 Introduction
2.2 Cases of adsorption
2.3 Adsorption versus Absorption
2.4 Factors affecting adsorption
2.5 Characteristics of adsorption
2.6 Types of adsorption
2.7 Adsorption Isotherm
2.8 Determination of surface area of adsorbent Brunauer- Emmett-Teller (BET) theory
2.9 Application of adsorption

3. Errors in Quantitative Analysis 
3.1 Introduction
3.2 Errors
3.3 Accuracy
3.4 Methods of Expressing Precision
3.5 Classification of Errors
3.6 Significant figures and computations
3.7 Distribution of Random errors
3.8 Reliability of Result

4. Volumetric Analysis 
4.1 Introduction to Volumetric Analysis
4.2 Method for Expressing Concentration of a solution
4.3 Unit of normalityis equivalents/liter or milliequivalents / milliliter
4.4 Classifications of reactions in volumetric analysis
4.5 Preparation of standard solutions
4.6 Primary and Secondary standard substances
4.7 Instrumental analysis
4.8 Types of volumetric analysis methods
4.9 Acid-Base (neutralization) titrations
4.10 Theory of acid-base indicators
4.11 Preparation of Indicator solution
4.12 Neutralization (Titration) Curves
4.13 Neutralization titrations (Acid Base Titrations)
4.14 Complexometric titrations
4.15 Redox Titrations
4.16 Precipitation titrations
4.17 Preparation of standard solution of oxalic acid (O.OSN) and to standardise approx. 0.05 N KMnO4 solution


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