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TYBSc Semester VI

CH-601 | Physical Chemistry – II

T.Y.B.Sc. | Sem VI | Chemistry

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T.Y.B.Sc. | Sem VI | CH-601
Physical Chemistry – II

It gives us an immense pleasure to handover this book in the hands of T.Y.B.Sc Chemistry students studying under Savitribai Phule Pune University, Pune. This book is purely based on the curriculum of T.Y.B.Sc Chemistry Semester-II for the subject CH-601 Physical Chemistry-II. The main aim while writing this book was to prepare the topics from the syllabi in simple and facile language in order to enhance the interest of the students towards the Physical Chemistry and at the same time to get the basic knowledge of various instrumental techniques used in the industrial sectors. We feel that both needs of students have been achieved in this textbook.
The chapters in this book cover all the syllabi points in very simplified way. To make the learning easy we have added figures, reactions, tables, graphs and all necessary things which will boost students understanding level of the subject. While writing this book care is also taken students should achieve the learning objective of each and every topic as per the curriculum. In every topic application of the given technique is also added which help the student to get idea about relevance of that specific technique in industrial sector and indirectly in our day to day life.

1. Electrochemical Cells 
1.1 Introduction
1.2 Salt Bridge
1.3 Conventions used in representing and construction of electrochemical cells
1.4 Reversible and Irreversible cells
1.5 Measurement of EMF
1.6 Standard cells
1.7 Reference Electrode
1.8 Expression for electrode potential or e.m.f. of electrochemical cell (Nernst Equation)
1.9 Types of electrodes
1.10 The sign convention for electrode potentials Standard Electrode
1.11 Thermodynamics of Reversible cells and Reversible Electrodes
1.12 EMF and equilibrium constant of a cell reaction
1.13 Electrochemical Series (Electromotive series)
1.14 Concentration Cells
1.15 Liquid Junction Potential or Diffusion Potential
1.16 Applications of emf measurements
1.17 Potentiometric Titrations
1.18 Batteries
1.19 Primary Batteries
1.20 Secondary Batteries
1.21 Applications of Secondary Batteries
1.22 Fuel Cells
1.23 Of Battery Vs Fuel Cell

2. Crystal structure 
2.1 Introduction
2.2 Types of Solids: Isotropy and Anisotropy
2.3 Laws of crystallography
2.4 Weiss and Miller Indices
2.5 Crystal Structure
2.6 Parameters of the Unit Cells
2.7 Cubic Unit Cells (a)
2.8 Calculation of Mass of the Unit Cell
2.9 Methods of Crystal structure analysis
2.10 Determination of crystal structure of NaCl by Bragg’s method
2.11 Calculation of d and λ for a crystal system

3. Nuclear Chemistry 
3.1 Introduction
3.2 Radioactivity
3.3 Types of Radiations
3.4 Detection and measurement of radioactivity
3.5 Nuclear / Nucleus structure
3.6 Classification of Nuclides
3.7 Types of Radioactive Decay
3.8 Kinetics of radioactive decay
3.9 Half-life and mean life period
3.10 The energy released in a nuclear reaction, Mass Defect, Nuclear Binding Energy
3.11 Applications of Radio-isotopes as tracers


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