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TYBSc Semester VI

CH-607 | Organic Chemistry – II

T.Y.B.Sc. | Sem VI | Chemistry

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T.Y.B.Sc. | Sem VI | CH-607
Organic Chemistry – II

It’s a great pleasure for us to present this book Organic Chemistry-II
(CH 607, Semester VI) for T.Y.B.Sc. Chemistry students of the Savitribai Phule Pune University, Pune. This book is written as per the revised syllabus of Savitribai Phule Pune University, Pune to be implemented from June 2021.
We have tried to explain the concepts and information in lucid language so that students could understand it easily. Many senior faculty members have inspired us to perform this duty. We feel it’s not a new creations but presentation in simple form for the better understanding of students.

1. Introduction to Spectroscopy 
1.1 Introduction
1.2 Meaning of spectroscopy
1.3 Nature of electromagnetic radiations
1.4 Regions of electromagnetic spectrum
1.5 Interaction of electromagnetic radiations with molecules

2. Ultra Violet and Visible Spectroscopy 
2.1 Introduction
2.2 Nature of UV spectrum
2.3 Electronic excitations / transitions
2.4 Terms used in UV spectroscopy
2.5 Effect of conjugation on UV bands
2.6 Calculation of λmax for diene system (By Woodward and Fieser rule)
2.7 Applications of UV spectroscopy

3. Infra-Red Spectroscopy 
3.1 Introduction
3.2 Principle of IR Spectroscopy
3.3 Types of molecular vibrations
3.4 Regions of IR spectrum
3.5 Characteristic IR absorption bands (IR spectra) for functional groups
3.6 Effect of substitution on >C=O stretching absorptions
3.7 Applications of IR spectroscopy

4. Nuclear Magnetic Resonance Spectroscopy (PMR) 
4.1 Introduction
4.2 Principles of NMR spectroscopy
4.3 Chemical shift (Position of NMR Signal)
4.4 Integration (Peak area)
4.5 Spin–spin coupling (splitting)
4.6 Coupling constant ‘J’
4.7 Applications of NMR spectroscopy

5. Combined problems based on U.V., I.R. and NMR 

6. Stereochemistry of Disubstituted Cyclohexane and Decalin 
6.1 Introduction
6.2 Geometrical and optical isomerism of 1,3- dimethyl and 1,4-dimethyl cyclohexane
6.3 Decalin (C10H18) (Decahydronaphthalene)


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